課程資料
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E417 無機化學(二)
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開課學期：1102
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開課班級：
化學系 3
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授課教師：蔡振彥
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必修
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學期課
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學分數：3.0
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大義 0306 星期二 12:10-15:00
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E417 INORGANIC CHEMISTRY(2)
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2022 Spring
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Department of Chemistry 3
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Professor：TSAI, CHEN-YEN
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Required
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Semester
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Credits:
3.0
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Da Yi 0306 Tuesday 12:10-15:00
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發展願景
傳揚中華文化，促進跨領域創新，與時精進，邁向國際
It is our objective to promote Chinese culture, enhance cross-disciplinary innovation, seek constant advancement, and embrace global community.
辦學宗旨
秉承質樸堅毅校訓，承東西之道統，集中外之精華，研究高深學術, 培養專業人才，服務社會，致力中華文化之發揚, 促進國家發展.
Based on our motto—“Temperament, Simplicity, Strength, and Tenacity,” “inheriting the merits of the East and the West” and “absorbing the essence of Chinese and foreign cultures,” we make it our mission to pursue advanced research, develop professional talents, serve the society, promote Chinese culture and support national development.
校教育目標
校基本素養
校核心能力
院教育目標
奠定自然科學基礎培養後續學習能力
強化理論與實務並重的多元課程
推動跨領域學習
促進國際化教學提升學生競爭力
院核心能力
自然科學知識的能力
理論與實務結合的能力
國際化與團隊溝通合作的能力
多元整合的能力
系教育目標
培育化學相關產業之專業人才Cultivate professional talents in chemical-related industries
系核心能力
化學基本專業知識Basic professional knowledge of chemistry
實驗技巧與儀器操作能力Experimental skills and instrument operation ability
團隊合作與溝通能力Teamwork and communication skills
口語表達與書面報告撰寫能力Oral expression and report writing skills
課程目標
引導學生熟悉無機化學中之配位化學 有機金屬化學等基礎知識之基本內容 並充份應用於催化及材料化學領域。
課程能力
化學基本專業知識Basic professional knowledge of chemistry (比重 70%)
實驗技巧與儀器操作能力Experimental skills and instrument operation ability (比重 10%)
團隊合作與溝通能力Teamwork and communication skills (比重 10%)
口語表達與書面報告撰寫能力Oral expression and report writing skills (比重 10%)
課程概述
本課程為第二學期的基礎無機化學，延續上學期之無機理論，擴充至過渡金屬元素。 主要聚焦於無機配位化學與過渡金屬元素化學之基本觀念說明及推導，同時引入無機化學在催化反應、材料化學及生化之應用。主要內容包括配位化學之結構、鍵結、電子光譜、反應機構、有機金屬化學、反應與催化、有機金屬化學、生物無機化學等。並強調無機化學與其他化學領域及一般應用。
學習重點: magnetic susceptibility, valence bond theory, crystal field theory, ligand field theory, ligand field stabilization energy (LFSE), π back-bonding, spectrochemical series, Jahn-Teller effect, angular overlap model, molar absorptivity, Russell-Saunders coupling, spin-orbit coupling, spin multiplicity, free-ion term, Hund’s rules, selection rule, Laporte selection rule, spin selection rule, charge transfer to metal (CTTM), ligand to metal charge transfer (LMCT), charge transfer to ligand (CTTL), metal to ligand charge transfer (MLCT), Tanabe-Sugano Diagrams, principle of microscopic reversibility, steady-state approximation, free energy of activation, enthalpy (heat) of activation, entropy of activation, kinetically labile or inert (robust), thermodynamically stable or unstable, dissociation (D), association (A), dissociative interchange (Id), associative interchange (Ia), aquation, anation, ligand field activation energy (LFAE), conjugate base mechanism (SN1CB), trans effect, trans influence, inner-sphere reaction, outer-sphere reaction, cluster compounds, ferrocene, fullerene, carbene complex, carbyne complex.
The course will cover a variety of coordination compounds, organometallic compounds and reactions, focusing on mechanisms in organometallic reactions. Applications of coordination chemistry and organometallic compounds in homogeneous catalysis, polymerization, and metathesis. During the course, students will learn the fundamental knowledge in this field.
授課內容
本課程為第二學期的基礎無機化學，延續上學期之無機理論，擴充至過渡金屬元素。 主要聚焦於無機配位化學與過渡金屬元素化學之基本觀念說明及推導，同時引入無機化學在催化反應、材料化學及生化之應用。主要內容包括配位化學之結構、鍵結、電子光譜、反應機構、有機金屬化學、反應與催化、有機金屬化學、生物無機化學等。並強調無機化學與其他化學領域及一般應用。
The course will cover a variety of the basics and outlines of homogeneous catalysts (metal complexes) and catalytic reactions. Applications of coordination chemistry and organometallic compounds in homogeneous catalysis, polymerization, and metathesis.
授課方式
投影片為主並利用專用講義來輔助教學
評量方式
上課用書
（師生應遵守智慧財產權及不得非法影印）
G. L. Miessler and D. A. Tarr, “Inorganic Chemistry”
參考書目
（師生應遵守智慧財產權及不得非法影印）
R. H. Crabtree, “The Organometallic Chemistry of the Transition Metals”,
C. M. Lukehart, “Fundamental Transition Metal Organometallic Chemistry”, Springer, 1990
P. Collman, “Principles and Applications of Organometallic Chemistry”,
Cotton, “Chemical Application of Group Theory”，
Transition Metal d‑Orbital Splitting Diagrams: An Updated
Educational Resource for Square Planar Transition Metal Complexes
DOI: 10.1021/acs.jchemed.5b00542
J. Chem. Educ. 2016, 93, 118−121
課程需求
要考試
三次考試各佔25%
平時點名及測驗佔25%
輔導時間
- 星期一 13:00-15:00
- 星期二 15:00-16:00
- 星期三 12:00-13:00 15:00-16:00
- 星期五 08:00-09:00
教師聯絡資訊
Email：czy21@ulive.pccu.edu.tw
分機：25314
課程進度
| 2022/02/22 | Ch9:Coordination Chemistry I:Structures and Isomers指定研讀資料Inorganic Chemistry pp341 - pp365 |
| 2022/03/01 | Ch9:Coordination Chemistry I:Structures and Isomers指定研讀資料Inorganic Chemistry pp366 - pp388 |
| 2022/03/08 | Ch10:Coordination Chemistry II:Bonding指定研讀資料Inorganic Chemistry pp389 - pp414 |
| 2022/03/15 | Ch10:Coordination Chemistry II:Bonding指定研讀資料Inorganic Chemistry pp415 - pp440 |
| 2022/03/22 | Ch11:Coordination Chemistry III:Electronic Spectra指定研讀資料Inorganic Chemistry pp441 - pp459 |
| 2022/04/12 | Ch11:Coordination Chemistry III:Electronic Spectra指定研讀資料Inorganic Chemistry pp460 - pp476 |
| 2022/04/19 | Ch12:Coordination Chemistry IV:Reactions and Mechanisms (期中考週)指定研讀資料Inorganic Chemistry pp477 - pp496 |
| 2022/04/26 | Ch12:Coordination Chemistry IV:Reactions and Mechanisms指定研讀資料Inorganic Chemistry pp497 - pp516 |
| 2022/05/03 | Ch13:Organometallic ChemistryIV:Reactions and Mechanisms指定研讀資料Inorganic Chemistry pp517 - pp536 |
| 2022/05/10 | Ch13:Organometallic Chemistry指定研讀資料Inorganic Chemistry pp537 - pp556 |
| 2022/05/24 | Ch13:Organometallic Chemistry指定研讀資料Inorganic Chemistry pp557 - pp588 |
| 2022/05/31 | Ch14:Organometallic Reaction and Catalysis指定研讀資料Inorganic Chemistry pp589 - pp603 |
| 2022/06/07 | Ch14:Organometallic Reaction and Catalysis指定研讀資料Inorganic Chemistry pp604 - pp617 |
| 2022/06/14 | Ch14:Organometallic Reaction and Catalysis指定研讀資料Inorganic Chemistry pp618 - pp629 |